{"id":219,"date":"2025-04-16T15:38:07","date_gmt":"2025-04-16T06:38:07","guid":{"rendered":"https:\/\/gpu-advchem.jp\/?p=219"},"modified":"2025-04-23T11:31:40","modified_gmt":"2025-04-23T02:31:40","slug":"%e5%a4%9a%e6%a7%98%e3%81%aa%e6%9d%90%e6%96%99%e3%81%ab%e5%8a%b9%e7%8e%87%e7%9a%84%e3%81%ab%e3%83%91%e3%83%a9%e3%82%b8%e3%82%a6%e3%83%a0%e3%82%92%e6%8b%85%e6%8c%81%e5%8f%af%e8%83%bd%e3%81%aa%e5%89%8d","status":"publish","type":"post","link":"https:\/\/gpu-advchem.jp\/?p=219","title":{"rendered":"\u591a\u69d8\u306a\u6750\u6599\u306b\u52b9\u7387\u7684\u306b\u30d1\u30e9\u30b8\u30a6\u30e0\u3092\u62c5\u6301\u53ef\u80fd\u306a\u524d\u99c6\u4f53\uff08Pd-80\uff09\u306e\u958b\u767a\u3068\u3001\u6301\u7d9a\u7684\u30d5\u30ed\u30fc\u89e6\u5a92\u306e\u5275\u88fd"},"content":{"rendered":"\n<h3 class=\"wp-block-heading\"><span style=\"font-family: verdana, geneva, sans-serif;\"><strong>\u6982\u8981<\/strong><\/span><\/h3>\n\n\n\n<p><span style=\"font-family: verdana, geneva, 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style=\"font-family: verdana, geneva, sans-serif;\">\u56fa\u4f53\u89e6\u5a92\u5145\u586b\u5f0f\u9023\u7d9a\u30d5\u30ed\u30fc\u53cd\u5fdc\u3067\u306f\u3001\u5805\u7262\u3067\u9ad8\u6d3b\u6027\u306e\u4e0d\u5747\u4e00\u7cfb\u91d1\u5c5e\u89e6\u5a92\u306e\u958b\u767a\u304c\u6c42\u3081\u3089\u308c\u3066\u3044\u307e\u3059\u3002\u6211\u3005\u306f\u9162\u9178\u30d1\u30e9\u30b8\u30a6\u30e0 [Pd(OAc)2] \u3092Pd\u6e90\u3001\u30e1\u30bf\u30ce\u30fc\u30eb\u3092\u6eb6\u5a92\u517c\u9084\u5143\u5264\u3068\u3057\u305f\u542b\u6d78\u5f0fPd(0)\u62c5\u6301\u6cd5\u3092\u78ba\u7acb\u3057\u3001\u69d8\u3005\u306a\u4e0d\u5747\u4e00\u7cfbPd\u89e6\u5a92\u3092\u958b\u767a\u30fb\u4e0a\u5e02\u3057\u3066\u304d\u307e\u3057\u305f\u3002\u3057\u304b\u3057Pd\u3068\u62c5\u4f53\u306e\u76f8\u4e92\u4f5c\u7528\u304c\u5f31\u3044\u3068\u3001Pd\u7c92\u5b50\u304c\u62c5\u4f53\u8868\u9762\u306b\u5438\u7740\u3059\u308b\u3053\u3068\u306a\u304f\u6790\u51fa\u30fb\u6c88\u6bbf\u3059\u308b\u3068\u3044\u3046\u8ab2\u984c\u304c\u3042\u308a\u307e\u3059\u3002<\/span><\/p>\n\n\n\n<p><span style=\"font-family: verdana, geneva, sans-serif;\">\u672c\u7814\u7a76\u3067\u306f\u3001\u30c6\u30c8\u30e9\u30ad\u30b9\u30c8\u30ea\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u30d1\u30e9\u30b8\u30a6\u30e0 [Pd(PPh<sub>3<\/sub>)<sub>4<\/sub>] \u3092\u52a0\u71b1\u9178\u5316\u51e6\u7406\u3057\u3066\u5f97\u3089\u308c\u305f\u7070\u8272\u7c89\u672b (Pd-80) \u3092\u7528\u3044\u3001cordierite\u7c89\u672b (2MgO\u00b72Al<sub>2<\/sub>O<sub>3<\/sub>\u00b75SiO<sub>2<\/sub>) \u3068\u3068\u3082\u306bCHCl<sub>3<\/sub>\u4e2d\u3067\u64b9\u62cc\u3059\u308b\u3053\u3068\u3067\u3001Pd\/cordierite\u89e6\u5a92\u3092\u8abf\u88fd\u3059\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002Pd-80\u306f\u3001\u6bd4\u8868\u9762\u7a4d\u304c\u5c0f\u3055\u3044\u30b1\u30a4\u7d20\u3001SiC\u3001\u6709\u6a5f\u30dd\u30ea\u30de\u30fc\u306a\u3069\u3001\u62c5\u4f53\u306e\u69cb\u6210\u5143\u7d20\u3084\u8868\u9762\u306e\u72b6\u614b\u306b\u4f9d\u5b58\u305b\u305aPd\u7a2e\u3092\u5747\u4e00\u306b\u62c5\u6301\u3059\u308b\u3053\u3068\u304c\u53ef\u80fd\u3067\u3059\u3002<\/span><\/p>\n\n\n\n<p><span style=\"font-family: verdana, geneva, sans-serif;\">Pd\/cordierite\u3092\u5145\u586b\u3057\u305f\u89e6\u5a92\u30ab\u30fc\u30c8\u30ea\u30c3\u30b8\u3092\u30d5\u30ed\u30fc\u5f0f\u63a5\u89e6\u9084\u5143\u306b\u9069\u7528\u3057\u305f\u7d50\u679c\u3001\u9577\u6642\u9593\u306b\u308f\u305f\u308a\u9ad8\u3044\u89e6\u5a92\u6d3b\u6027\u3092\u793a\u3057\u3001\u4f8b\u3048\u3070\u30cb\u30c8\u30ed\u30d9\u30f3\u30bc\u30f3\u8a98\u5c0e\u4f53 (1) \u306e\u63a5\u89e6\u9084\u5143\u3067\u306f\u3001150\u6642\u9593\u4ee5\u4e0a90%\u3092\u4e0b\u56de\u308b\u3053\u3068\u306a\u304f\u30a2\u30cb\u30ea\u30f3\u8a98\u5c0e\u4f53 (2) \u3078\u3068\u5909\u63db\u3067\u304d\u307e\u3057\u305f\u3002\u6700\u7d42\u7684\u306b\u7d0435 g\u306e\u30a2\u30df\u30f3\u304c\u5f97\u3089\u308c\u3001\u30d1\u30e9\u30b8\u30a6\u30e0\u306e\u30ea\u30fc\u30c1\u30f3\u30b0\u306f\u5168\u304f\u78ba\u8a8d\u3055\u308c\u307e\u305b\u3093\u3067\u3057\u305f\u3002\u89e6\u5a92\u56de\u8ee2\u6570 (TON) \u306f61,090\u3001\u89e6\u5a92\u56de\u8ee2\u7387 (TOF) \u306f231\u6bce\u6642\u3001\u7a7a\u6642\u6570\u91cf (STY) \u306f240\u306b\u9054\u3057\u3001Pd\/cordierite\u306e\u7269\u7406\u7684\u30fb\u5316\u5b66\u7684\u306a\u5805\u7262\u6027\u3068\u9ad8\u3044\u89e6\u5a92\u6d3b\u6027\u304c\u5b9f\u7528\u57df\u3067\u5b9f\u8a3c\u3055\u308c\u307e\u3057\u305f\u3002<\/span><\/p>\n\n\n\n<p><span style=\"font-family: verdana, geneva, sans-serif;\">\u4eca\u56de\u3001\u79c1\u305f\u3061\u306f\u69d8\u3005\u306a\u7121\u6a5f\u304a\u3088\u3073\u6709\u6a5f\u6750\u6599\u306b\u30d1\u30e9\u30b8\u30a6\u30e0\u3092\u5bb9\u6613\u306b\u62c5\u6301\u3067\u304d\u308b\u65b0\u305f\u306a\u30d1\u30e9\u30b8\u30a6\u30e0\u524d\u99c6\u4f53\u3001\u30d1\u30e9\u30b8\u30a6\u30e0\u30a8\u30a4\u30c6\u30a3\uff08Pd-80\uff09\u3092\u958b\u767a\u3057\u307e\u3057\u305f\u3002\u3053\u306e\u524d\u99c6\u4f53\u306f\u4eca\u5f8c\u306e\u89e6\u5a92\u958b\u767a\u306b\u304a\u3044\u3066\u975e\u5e38\u306b\u6709\u671b\u3067\u3001\u6301\u7d9a\u53ef\u80fd\u306a\u89e6\u5a92\u30d7\u30ed\u30bb\u30b9\u3078\u306e\u8ca2\u732e\u304c\u671f\u5f85\u3055\u308c\u307e\u3059\u3002\u3055\u3089\u306b\u3001\u958b\u767a\u3055\u308c\u305fPd\/cordierite\u306f\u512a\u308c\u305f\u5b98\u80fd\u57fa\u9078\u629e\u7684\u63a5\u89e6\u9084\u5143\u89e6\u5a92\u3068\u3057\u3066\u9577\u6642\u9593\u306e\u9023\u7d9a\u30d5\u30ed\u30fc\u53cd\u5fdc\u306b\u5bfe\u5fdc\u3067\u304d\u3001\u30a8\u30cd\u30eb\u30ae\u30fc\u30ed\u30b9\u306e\u4f4e\u6e1b\u3084\u30d1\u30e9\u30b8\u30a6\u30e0\u4f7f\u7528\u91cf\u306e\u524a\u6e1b\u304c\u53ef\u80fd\u306a\u89e6\u5a92\u3068\u3057\u3066\u3001\u5de5\u696d\u7684\u306a\u5fdc\u7528\u3067\u3082\u9ad8\u3044\u671f\u5f85\u304c\u5bc4\u305b\u3089\u308c\u307e\u3059\u3002<\/span><\/p>\n\n\n\n<figure class=\"wp-block-image\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"508\" src=\"https:\/\/gpu-advchem.jp\/wp-content\/uploads\/2025\/04\/ReactChem_JP-1024x508.jpg\" alt=\"\" class=\"wp-image-221\" srcset=\"https:\/\/gpu-advchem.jp\/wp-content\/uploads\/2025\/04\/ReactChem_JP-1024x508.jpg 1024w, https:\/\/gpu-advchem.jp\/wp-content\/uploads\/2025\/04\/ReactChem_JP-300x149.jpg 300w, https:\/\/gpu-advchem.jp\/wp-content\/uploads\/2025\/04\/ReactChem_JP-768x381.jpg 768w, https:\/\/gpu-advchem.jp\/wp-content\/uploads\/2025\/04\/ReactChem_JP.jpg 1299w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<p><\/p>\n\n\n\n<h3 class=\"wp-block-heading\"><span style=\"font-family: verdana, geneva, sans-serif;\"><strong>\u672c\u7814\u7a76\u6210\u679c\u306e\u30dd\u30a4\u30f3\u30c8<\/strong><\/span><\/h3>\n\n\n\n<ul class=\"wp-block-list\">\n<li><span style=\"font-family: verdana, geneva, sans-serif;\">\u69d8\u3005\u306a\u7121\u6a5f\u304a\u3088\u3073\u6709\u6a5f\u6750\u6599\u306b\u30d1\u30e9\u30b8\u30a6\u30e0\u3092\u5bb9\u6613\u306b\u62c5\u6301\u3067\u304d\u308b\u65b0\u305f\u306a\u30d1\u30e9\u30b8\u30a6\u30e0\u524d\u99c6\u4f53\u3001\u30d1\u30e9\u30b8\u30a6\u30e0\u30a8\u30a4\u30c6\u30a3\u3092\u958b\u767a\u3057\u305f\u3002\u4eca\u5f8c\u306e\u89e6\u5a92\u958b\u767a\u306b\u304a\u3044\u3066\u975e\u5e38\u306b\u6709\u671b\u306a\u524d\u99c6\u4f53\u3067\u3042\u308b\u3053\u3068\u304c\u5f37\u304f\u793a\u3055\u308c\u3001\u6301\u7d9a\u53ef\u80fd\u306a\u89e6\u5a92\u30d7\u30ed\u30bb\u30b9\u3078\u306e\u8ca2\u732e\u304c\u671f\u5f85\u3055\u308c\u308b\u3002<\/span><\/li>\n\n\n\n<li><span style=\"font-family: verdana, geneva, sans-serif;\">Pd-80\u3067\u8abf\u88fd\u3057\u305fPd\/cordierite\u89e6\u5a92\u306f\u3001\u512a\u308c\u305f\u5b98\u80fd\u57fa\u9078\u629e\u7684\u63a5\u89e6\u9084\u5143\u89e6\u5a92\u3068\u3057\u3066\u6a5f\u80fd\u3057\u3001\u9577\u6642\u9593\u9023\u7d9a\u30d5\u30ed\u30fc\u53cd\u5fdc\u3082\u53ef\u80fd\u3067\u3042\u308b\u305f\u3081\u3001\u30a8\u30cd\u30eb\u30ae\u30fc\u30ed\u30b9\u306e\u4f4e\u6e1b\u3084\u30d1\u30e9\u30b8\u30a6\u30e0\u4f7f\u7528\u91cf\u306e\u524a\u6e1b\u304c\u53ef\u80fd\u306a\u89e6\u5a92\u3068\u3057\u3066\u3001\u5de5\u696d\u7684\u306b\u3082\u671f\u5f85\u3055\u308c\u308b\u3002<\/span><\/li>\n<\/ul>\n\n\n\n<h3 class=\"wp-block-heading\"><span style=\"font-family: verdana, geneva, sans-serif;\">\u8ad6\u6587\u60c5\u5831<\/span><\/h3>\n\n\n\n<ul class=\"wp-block-list\">\n<li><span style=\"font-family: verdana, geneva, sans-serif;\"><strong>\u96d1\u8a8c\u540d<\/strong>\uff1aChemSusChem<\/span><\/li>\n\n\n\n<li><span style=\"font-family: verdana, geneva, sans-serif;\"><strong>\u8ad6\u6587\u540d<\/strong>\uff1aStable and Versatile Pd Precursors for the Preparation of Robust Pd Catalysts under Continuous-Flow<\/span><\/li>\n\n\n\n<li><span style=\"font-family: verdana, geneva, sans-serif;\"><strong>\u8457\u8005<\/strong>\uff1aNaoya Sakurada, Kwihwan Kobayashi, Yuka Abe, Kosuke Niwa, Takashi Yokoyama, Tsuyoshi Yamada, Takashi Ikawa, Hironao Sajiki<\/span><\/li>\n\n\n\n<li><span style=\"font-family: verdana, geneva, sans-serif;\"><strong>DOI\u756a\u53f7<\/strong>\uff1a<a href=\"https:\/\/doi.org\/10.1002\/cssc.202401859\" target=\"_blank\" rel=\"noopener noreferrer\">https:\/\/doi.org\/10.1002\/cssc.202401859<\/a><\/span><\/li>\n<\/ul>\n\n\n\n<p><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6982\u8981 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[&hellip;]<\/p>\n","protected":false},"author":3,"featured_media":221,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"sns_share_botton_hide":"","vkExUnit_sns_title":"","_vk_print_noindex":"","sitemap_hide":"","_veu_custom_css":"","veu_display_promotion_alert":"common","vkexunit_cta_each_option":"","footnotes":""},"categories":[10],"tags":[11],"class_list":["post-219","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-10","tag-11"],"veu_head_title_object":{"title":"","add_site_title":""},"_links":{"self":[{"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=\/wp\/v2\/posts\/219","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=219"}],"version-history":[{"count":3,"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=\/wp\/v2\/posts\/219\/revisions"}],"predecessor-version":[{"id":226,"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=\/wp\/v2\/posts\/219\/revisions\/226"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=\/wp\/v2\/media\/221"}],"wp:attachment":[{"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=219"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=219"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/gpu-advchem.jp\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=219"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}